Fischer-Tropsch synthesis of hydrocarbons over zeolitesupported ruthenium catalysts.
نویسندگان
چکیده
منابع مشابه
Fischer-Tropsch Synthesis of Hydrocarbons Using Iron-Mordenite Catalysts
Fischer-tropsch catalysts with high activity and selectivity for olefins were produced using mordenite type SiO2/Al2O3= 12, 20, 28, 62 zeolite supported iron carbonyl compounds and were characterized by X-ray powder diffraction. The adsorptionof volatile Fe(CO)5 on the support surface was carried out under vacuum at room temperature. Reduction les...
متن کاملFischer-Tropsch Synthesis on Bimetallic Ruthenium-Gold Catalysts
The effect of Au in the behavior of Ru as a Fischer-Tropsch catalyst was studied. Two series of catalysts were investigated, one supported on Si02 and the other on MgO. Au did not seem to alter the product distribution on Ru at pressures up to 1 MPa and in the temperature range 490-570 K. However, the turnover frequencies for both CO hydrogenation and methanation showed a precipitous drop with ...
متن کاملfischer-tropsch synthesis of hydrocarbons using iron-mordenite catalysts
fischer-tropsch catalysts with high activity and selectivity for olefins were produced using mordenite type sio2/al2o3= 12, 20, 28, 62 zeolite supported iron carbonyl compounds and were characterized by x-ray powder diffraction. the adsorptionof volatile fe(co)5 on the support surface was carried out under vacuum at room temperature. reduction les were monitored by vibrating sample magnetometer...
متن کاملMechanistic role of water on the rate and selectivity of Fischer-Tropsch synthesis on ruthenium catalysts.
Water increases Fischer-Tropsch synthesis (FTS) rates on Ru through H-shuttling processes. Chemisorbed hydrogen (H*) transfers its electron to the metal and protonates the O-atom of CO* to form COH*, which subsequently hydrogenates to *HCOH* in the kinetically relevant step. H2 O also increases the chain length of FTS products by mediating the H-transfer steps during reactions of alkyl groups w...
متن کاملRuthenium Modification on Mn and Zr-Modified Co/SiO2 Catalysts for Slurry-Phase Fischer-Tropsch Synthesis
The addition of Ru to Mn and Zr-modified Co/SiO2 catalysts, while applying different preparation orders and loading amounts, was investigated as a means of enhancing the Fischer-Tropsch synthesis reaction. The coimpregnation of Zr/SiO2 with Co, Mn and Ru gave the most attractive catalytic properties. This can be attributed to the higher dispersion of Co metal resulting from the coimpregnation o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of The Japan Petroleum Institute
سال: 1985
ISSN: 0582-4664
DOI: 10.1627/jpi1958.28.114